In the course of the study, a method for obtaining a composite PVDF film with titanium dioxide microparticles was proposed. The work studied the effect of adding different amounts of titanium dioxide microparticles on the surface morphology and roughness of the resulting material. The spectral characteristics of PVDF/TiO2 films were studied. The electrophysical characteristics of the films were analyzed depending on the concentration of added titanium dioxide microparticles.